Ti-5Al-5V-5Mo-3Cr is a metastable titanium alloy of growing interest for high-performance structural and biomedical applications because of its attractive combination of strength, hardenability, toughness, and corrosion resistance. When processed by laser powder bed fusion (L-PBF), its final performance is governed by the interaction between powder characteristics, rapid solidification, melt-pool stability, defect formation, surface condition, and phase evolution. In this study, as-built Ti-5Al-5V-5Mo-3Cr specimens were fabricated using a TruPrint 1000 TRUMPF laser powder bed fusion system and experimentally assessed to establish qualitative relationships between feedstock quality, The experimental programme combines powder analysis, density measurement, X-ray computed tomography, surface roughness evaluation, optical microscopy, scanning electron microscopy, X-ray diffraction, nanoindentation, tensile testing, and corrosion testing.