Polymer Pen Lithography (PPL) which is a hybrid of Dip-Pen Nanolithography (DPN) and soft lithography technique namely Microcontact Printing (µCP) has been tested for its pros and cons in patterning functional phospholipids under varying instances using high resolution characterization techniques. Although, having the advantage of simultaneously printing at several points of the substrate covering area on the order of millimeter by employing a Polydimethylsiloxane (PDMS) stamp however PPL is yet to make a mark to prove its ability to have as high a feature size compactness and precision in comparison to cantilever based scanning probe lithography techniques such as its parent technique DPN.