Nanostructuring of a biobased diglycidyl ether of vanillin (DGEVA) was obtained by self-assembly of poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) (PEO-PPO-PEO) triblock copolymer. Preliminary studies on the synthesis of dihydroxyaminopropane of vanillyl alcohol (DHAVA) from the DGEVA were carried out. The use of DHAVA as curing agent for DGEVA epoxy systems was also investigated.