Bruna Nespola
Process design of a catalytic ammonia cracker for hydrogen generation.
Rel. Stefania Specchia, Marcus Rose. Politecnico di Torino, Corso di laurea magistrale in Ingegneria Chimica E Dei Processi Sostenibili, 2026
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Abstract
The global transition toward a low-carbon economy identifies hydrogen (H2) as a fundamental energy vector. However, critical challenges related to long-distance storage and transport limit its implementation on a global scale. In this context, ammonia (NH3) emerges as a strategic hydrogen carrier due to its high volumetric hydrogen density, ease of liquefaction, and well-established global logistics infrastructure. This thesis analyses the process design and simulation in Aspen Plus of a catalytic ammonia cracking process to produce 5 tons/day of high-purity hydrogen (99.9%). Given the strongly endothermic nature of the reaction, the study focuses on comparing two heat supply strategies: conventional thermal heating via combustion and electrical heating.
Regarding thermal heating, three combustion scenarios were evaluated (combustion of pure NH3, pure H2, or a mixture of both), integrating flammability limit studies with an analysis of nitrogen oxide (NOx) formation
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