The development of Smart Cities worldwide and the increasing issues related to sustainability and to the environment have pushed towards the electrification of transports, promoting a rapid advent of electric vehicles (EV) in the market. EVs are leading polluting emissions in the transport sector on a path towards zero, however, the charging of EVs’ battery has an enormous impact on power grids. High penetration of EVs can result in extreme loads that can alter electricity prices and suddenly increase bulk generation, which in turn generate more CO2 emissions if power plants still rely on fossil fuels. Therefore, high penetration without supervision and control strategies pose a threat to the sustainability of distribution networks.