Titanium alloys processed through laser powder bed fusion (LPBF) using in-situ alloying allow for a low-cost method to produce different microstructures and levels of solidification in titanium alloys. Pre-alloyed powder is not required to create these different alloys, as they are created using expensive powders. In this paper, iron additions of x = 1, 3, 5 weight percent were added to Ti6Al4V to explore how iron would affect both the processability of Ti6Al4V and the properties produced via LPBF. A process window was defined and an optimal processing condition was determined at P = 200 W, v = 800 mm/s, h = 0.105 mm, and t = 0.03 mm, which corresponds to VED ≈ 79.37 J/mm³.