Marco Dibenedetto
Optimization of MOF film deposition process and oxide µ-patterning via Atmospheric Pressure SALD/SMLD.
Rel. Barbara Onida, David Munoz-Rojas. Politecnico di Torino, Corso di laurea magistrale in Ingegneria Dei Materiali, 2022
Abstract
Metal-organic frameworks (MOFs) are an interesting class of self-assembled hybrid materials that are gaining more and more interest in several fields thanks to the tunable porosity and bandgap, mechanical and chemical stability, and low dielectric constant. MOF thin films are particularly interesting for applications such as microelectronics, gas sensing and filtration, photovoltaics, and catalysis. However, these applications are not always compatible with the wet-based chemistries typically used. Therefore, gas-based approaches such as CVD and ALD/MLD represent valid solutions. Nevertheless, Atmospheric Pressure Spatial Molecular layer deposition (AP-SMLD) could represent a faster and easier approach for the direct growth of MOF thin films, but it must be optimized yet.
Under this perspective, this study investigated the influence of the substrate and organic ligand bubbling temperatures, the scanning speed, and the influence of water during deposition and post-deposition treatments for the SMLD deposition of Zn(4-(5)-methylimidazole)2 films
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