Tommaso Serra
Single-Electron Phenomena in Electrochemistry of Biosensors.
Rel. Alberto Tagliaferro, Sandro Carrara. Politecnico di Torino, Corso di laurea magistrale in Nanotechnologies For Icts (Nanotecnologie Per Le Ict), 2020
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Abstract
??In this work, we modelled Coulomb blockade and Coulomb staircase phenomena starting from first-principles and taking advantage of Schrödinger-like problems knowledge. ??Coulomb blockade and staircase phenomena are physical effects related to the quantization of levels in a nanoparticle. In the past, experimental results concerning these phenomena have been modelled with either semiclassical or circuit-like models, which derive electrical parameters such as capacitances and resistances in order to reproduce the measured currents trends. ???? ??Our approach blossoms in the framework of quantum mechanics. As a first step, we studied a simplified model, which is often used to describe a similar quantum structure, in which discretized energy levels exist in the region enclosed between two one-dimensional potential energy barriers.
In this model, when electrons are forced to drift across the system under the effect of a bias voltage, they are able to tunnel across the first energy barrier to move to one of the available energy levels, eventually leaving the system by tunneling across the other barrier
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